科研团队(课题组):环境污染物控制化学
负责人:兰叶青,025-84396697,lanyq102@njau.edu.cn
研究方向:重金属污染物控制;有机污染物控制;新颖多功能材料研发;矿山酸性废水治理。
团队成员:李瑛副教授、国静讲师
团队简介:本研究团队由1位教授,1位副教授和1位讲师组成,所有成员均获得博士学位。本团队成员近年来一直从事重金属离子六价铬的还原去除,首次指出了在厌氧的反应体系中,硫化物的氧化产物单质S对硫化物还原Cr(VI)有极显著的催化加速作用。发现了不同金属离子对有机酸还原六价铬的不同催化作用机理。在有机污染物的降解方面,主要研究过渡金属离子(如Zn(II)和Cu(II)等)活化过硫酸钠或臭氧等氧化降解有机染料和有机合成中间体等。通过系列研究揭示了过渡金属离子的催化机理,明确了活化中间体和有关影响因素,从而为探索降解环境中的持久高毒的有机污染物的新技术提供科学依据。在新型功能材料的研究方面,目前正在研发介孔磁性材料作为砷,铬等高效吸附剂。采用插入、嫁接和合成等方法修饰或改性获得新型功能材料,这种吸附剂不仅具有优越的吸附性能,同时因具有高磁性,能显著提高吸附剂与废水间的分离效果。
近三年承担的重大、重点项目与课题:
1. 含重金属酸性矿山废水的生物矿化处理新技术原理(国家自然科学基金面上重点项目,时间:2017-2021,子项目负责人兰叶青)
2. 磁性氧化物基稀土纳米复合材料的制备及其高效去除水中砷的研究(国家自然科学基金青年科学基金项目,时间2017-2019,主持人李瑛)
3. Zn活化臭氧氧化降解有机污染物的研究(中央高校财政资助项目,时间2015-2017,主持人李瑛)
4. 锌活化过硫酸钠降解有机污染物机理及其效果研究(国家自然科学基金面上项目,时间2014-2015,主持人兰叶青)
5. 硅胶负载纳米锌降解水中有机污染物的效果及机理研究(国家自然科学基金青年科学基金项目,时间2014-2016,主持人国静)
近三年取得的代表性科研成果:
1. Jing Zhang, Yao Wu, Liping Liu, Yeqing Lan*. Rapid removal of p-chloronitrobenzene from aqueous solution by a combination of ozone with zero-valent zinc. Separation and Purification Technology. 2015, 151, 318–323.
2. Jing Zhang, Yao Wu, Chao Qin, Liping Liu, Yeqing Lan*. Rapid degradation of aniline in aqueous solution by ozone in the presence of zero-valent zinc. Chemosphere. 2015, 141, 258–264.
3. Jing Guo, Xue Chen, Ying Shi, Yeqing Lan*, Chao Qin.Rapid Photodegradation of Methyl Orange (MO) Assisted with Cu(II) and Tartaric Acid. Plos One. August, 2015,1-12.
4. Jing Guo, Chao Dong, Jing Zhang, Yeqing Lan*. Biogenic synthetic schwertmannite photocatalytic degradation of acid orange 7 (AO7) assisted by citric acid. Separation and Purification Technology. 2015, 143: 27–31.
5. Ying Li, Cheng Chen, Jing Zhang, Yeqing Lan *. Catalytic role of Cu(II) in the reduction of Cr(VI) by citric acid under an irradiation of simulated solar light. Chemosphere, 2015, 127: 87–92.
6. Ying Li, Hui Li, Ning Zhong, Guixiang Quan, Yeqing Lan*. Catalytic Roles of Mn(II) and Fe(III) in the Reduction of Cr(VI) by Mandelic Acid under an Irradiation of Simulated Solar Light. Water Environment Research, 2015, 87: 50-60.
7. Ying Li, Hui Li, Jing Zhang, Guixiang Quan,Yeqing Lan*. Efficient Degradation of Congo Red by Sodium Persulfate Activated with Zero-Valent Zinc. Water Air Soil Pollut. 2014, 225:2121
8. Hui Li, Jing Guo, Lijiao Yang, Yeqing Lan*. Degradation of methyl orange by sodium persulfate activated with zero-valent zinc. Separation and purification Technology. 2014, 132,168–173
9. Feng Yang, Jing Guo, Runan Dai, Yeqing Lan*. Oxidation of Cr(III)-citrate/tartrate complexes by δ-MnO2: Production of Cr(VI) and its impact factors. Geoderma. 2014, 213, 10–14.
10. Changyuan Yu, Jing Zhang, Xiaolei Wu, Yeqing Lan*, Lixiang Zhou. Cr(VI) removal by biogenic schwertmannite in continuous flow column. Geochemical Journal. 2014, 47, 1–7.
11. Na Chen, Yeqing Lan, Bo Wang, Jingdong Mao. Reduction of Cr (VI) by organic acids in the presence of Al (III). Journal of Hazardous Materials. 2013, 260, 150– 156.
12. Jing Guo, Ying Li, Runan Dai, Yeqing Lan*. Rapid reduction of Cr(VI) coupling with efficient removal of total chromium in the coexistence of Zn(0) and silica gel. Journal of Hazardous Materials. 2012,243: 265– 271.
13. Peng Zhou, Ying Li, Yuxiao Shen, Yeqing Lan*, Lixiang Zhou. Facilitating role of biogenetic schwertmannite in the reduction of Cr(VI) by sulfide and its mechanism. Journal of HazardousMaterials. 2012, 237– 238: 194– 198.
14. Danjun Jiang, Ying Li, Yong Wu, Pei Zhou, Yeqing Lan*, Lixiang Zhou. Photocatalytic reduction of Cr(VI) by small molecular weight organic acids over schwertmannite. Chemosphere. 2012, 89: 832–837.